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ChemInform Abstract: Generation and Typical Reactions of Thiocarbonyl Ylides

✍ Scribed by G. Mloston; H. Heimgartner


Publisher
John Wiley and Sons
Year
2001
Weight
24 KB
Volume
32
Category
Article
ISSN
0931-7597

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Generation and cyclization of thiocarbon
✍ Ahmed F. Khattab; Omar M. Ali; Ibrahim El-Sayed πŸ“‚ Article πŸ“… 2007 πŸ› John Wiley and Sons 🌐 English βš– 164 KB

## Abstract The unexpected 1,3‐benzodithiine derivatives **5b,c** were obtained from the reactions of trimethylsilyldiazomethane **2** with __C__‐sulfonyldithioformates, bearing pentachlorophenylthio group, **1b,c** via unprecedented cyclization of the transient thiocarbonyl ylides **4b,c**. While