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ChemInform Abstract: Generation and Diels—Alder Trapping of 4,5-Bis(bromomethylene)-4,5-dihydrothiazole.

✍ Scribed by K. JOUVE; F. PAUTET; M. DOMARD; H. FILLION

Publisher
John Wiley and Sons
Year
2010
Weight
32 KB
Volume
30
Category
Article
ISSN
0931-7597

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Generation and Diels-Alder Trapping of 4
Generation and Diels-Alder Trapping of 4,5-Bis(bromomethylene)-4,5-dihydrothiazole
✍ Karine Jouve; Félix Pautet; Monique Domard; Houda Fillion 📂 Article 📅 1998 🏛 John Wiley and Sons 🌐 English ⚖ 273 KB

Treatment of 4,5-bis(dibromomethyl)thiazole (1a) with of the cycloadditions between 2a and naphthoquinones 6 agrees with the predictions of the frontier molecular orbital sodium iodide in DMF led to 4,5-bis(bromomethylene)-4,5dihydrothiazole (2a). Trapping the latter in situ with theory. In contrast