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ChemInform Abstract: Fused Lactones as a Route to Functionalized 1-Substituted Indoles.

โœ Scribed by H. F. SCHUSTER; G. M. COPPOLA


Book ID
112021829
Publisher
John Wiley and Sons
Year
2010
Weight
29 KB
Volume
26
Category
Article
ISSN
0931-7597

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Pd(0)-Catalyzed Lactone Migration: A Facile Route to cis-Fused Hydrobenzofurans. -MCPBA-oxidation of the bicyclooctenones (I) under buffered conditions results in a regio-and chemoselective Baeyer-Villiger rearrangement to the lactones (II) which undergo a Pd(0)-catalyzed lactone migration for effi