ChemInform Abstract: Further Demonstration of the Higher Reactivity of the Vinyl Hydrogen Rather than the Allyl Hydrogen Towards Singlet Oxygen.

ChemInform Abstract: Abnormally High Rea

ChemInform Abstract: Abnormally High Reactivity of the Vinyl Hydrogen Toward Singlet Oxygen in a Twisted 1,3-Diene.

✍ H. MORI; K. IKOMA; Y. MASUI; S. ISOE; K. KITAURA; S. KATSUMURA 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 29 KB

Abnormally High Reactivity of the Vinyl Hydrogen Toward Singlet Oxygen in a Twisted 1,3-Diene. -Sensitized photooxidation of the twisted 1,3-dienes (I) results in formation of the allene via ene-reaction of the C-7 vinyl hydrogen together with the exo-methylene compounds (III) via reaction of the C