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ChemInform Abstract: Functionalized Emulsion and Suspension Polymer Particles: Nanoreactors for the Synthesis of Inorganic Materials.

✍ Scribed by L. MANZIEK; E. LANGENMAYR; A. LAMOLA; M. GALLAGHER; N. BRESE; N. ANNAN

Publisher
John Wiley and Sons
Year
2010
Weight
29 KB
Volume
30
Category
Article
ISSN
0931-7597

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✦ Synopsis

Functionalized Emulsion and Suspension Polymer Particles: Nanoreactors for the Synthesis of Inorganic Materials.

-Functionalized, cross-linked acrylic emulsion polymers are prepared from ethyl acrylate, methacrylic acid, and allylic methacrylate in aqueous media. They can be used as reaction vessels for inorganic reactions. This novel synthetic technique may be used with most metalic elements, and it is demonstrated for the formation of ZrO 2 , CeO 2 , LiMn 2 O 4 , and Ba 2 YCu 3 O 7 , as well as catalysts in the Au/Pt and Pt/CeO 2 systems. This technology provides unique control over stoichiometry, particle morphology, and crystalline phase. -(MANZIEK, L.;

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