ChemInform Abstract: Functional Conversion of Polybrominated Fullerenes.

✍ Scribed by C. S. LEE

• Publisher: John Wiley and Sons
• Year: 2010
• Weight: 26 KB
• Volume: 28
• Category: Article
• ISSN: 0931-7597
• DOI: 10.1002/chin.199706094

✦ Synopsis

Functional Conversion of Polybrominated Fullerenes.

-Treatment of polybrominated fullerene C60Br24 with AlBr3 in benzene at room temperature yields fullerated benzene. Under similar conditions, fullerated toluene and fluorobenzene are obtained. Polymethoxylated fullerene is produced from C60Br6 with excess methanolic KOH at 60 . degree.C. C60(PO(O-Et)2)n is formed from C60Br6 or C60Br24 and LiPO(O-Et)2 in THF at 0 • C. -(LEE,