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ChemInform Abstract: Free Radical-Mediated Ketone Synthesis from Alkyl Iodides via Sequential Radical Acylation Approach.

✍ Scribed by S. KIM; J.-Y. YOON


Publisher
John Wiley and Sons
Year
2010
Weight
31 KB
Volume
28
Category
Article
ISSN
0931-7597

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✦ Synopsis


Free Radical-Mediated Ketone Synthesis from Alkyl Iodides via Sequential Radical Acylation Approach.

-The first successful sequential radical acylation approach is demonstrated. It is a general approach for the synthesis of acyclic and cyclic ketones from alkyl iodides with the bis-sulfonyl oxime ether (II) under radical conditions. (II) appears to be the first example of a carbonyl equivalent geminal radical acceptor. -(KIM, S.;


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