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ChemInform Abstract: Free Radical Addition of α-Telluroesters to Alkenes.

✍ Scribed by Nobuaki Kambe; Li-Biao Han; Shin-ichi Fujiwara; Noboru Sonoda

Publisher
John Wiley and Sons
Year
2011
Weight
36 KB
Volume
42
Category
Article
ISSN
0931-7597

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✦ Synopsis

Abstract

The title reaction leads to the compounds (III), (VI), (VIII), and (X) and suppresses the competing olefin polymerization.

📜 SIMILAR VOLUMES

Free radical addition of α-telluroesters
Free radical addition of α-telluroesters to alkenes
✍ Nobuaki Kambe; Li-Biao Han; Shin-ichi Fujiwara; Noboru Sonoda 📂 Article 📅 2011 🏛 John Wiley and Sons 🌐 English ⚖ 92 KB 👁 1 views

## Abstract α‐(Phenyltelluro)esters **2** reacted with electron‐rich alkenes **3** in the presence of a catalytic amount of azobisisobutyronitrile (AIBN) as an initiator to give the corresponding addition products **4**. This carbotelluration of alkenes proceeded via a radical chain mechanism invol