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ChemInform Abstract: Formation of Highly Substituted Pyrrole Derivatives: An Unexpected Domino Reaction.

โœ Scribed by Claudia Wittland; Nikolaus Risch


Publisher
John Wiley and Sons
Year
2010
Weight
29 KB
Volume
30
Category
Article
ISSN
0931-7597

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โœฆ Synopsis


Formation of Highly Substituted Pyrrole Derivatives: An Unexpected Domino Reaction. -If the reaction is performed with 13 C methyl labeled amine (Ia), the carbon atom is found in the benzyl-substituted 3-position of pyrrole (IIIa). On the basis of this result a mechanism is proposed for the reaction. -(WITTLAND, CLAUDIA;


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Unexpected Formation of Substituted Anilides via Reactions of Trifluoroacetanilides with Lithium Reagents. -In connection with experiments to form a dithio reagent the title unexpected formation leading to compounds such as (III) is observed. Mechanistical aspects are discussed. -