ChemInform Abstract: Formation of Co3+ Octahedra and Tetrahedra in YBaCo4O8.1.
β Scribed by O. Chmaissem; H. Zheng; A. Huq; P. W. Stephens; J. F. Mitchell
- Publisher
- John Wiley and Sons
- Year
- 2008
- Weight
- 17 KB
- Volume
- 39
- Category
- Article
- ISSN
- 0931-7597
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Hydrate Borate. -Violet, air-and water-resistant crystals of the title compound are synthesized from a stoichiometric mixture of Co3O4 and H3BO3 (Walker-type multianvil apparatus, 6 GPa, 880 Β°C, 5 min). The new high--pressure phase is characterized by powder and single crystal XRD, IR, and Raman spe