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ChemInform Abstract: Formation of 3-Sulfonyl-Substituted Benzo[1]heptalene-2,4-diols from Heptalene-1,2-dicarboxylates and Lithiomethyl Phenyl Sulfones.

✍ Scribed by Marc Lutz; Anthony Linden; Khaled Abou-Hadeed; Hans-Juergen Hansen


Publisher
John Wiley and Sons
Year
2010
Weight
33 KB
Volume
30
Category
Article
ISSN
0931-7597

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✦ Synopsis


fused phenylcycloalkyl derivatives fused phenylcycloalkyl derivatives (rings with 3, 4, 7 or more members) Q 1040 45 -111 Formation of 3-Sulfonyl-Substituted Benzo[1]heptalene-2,4-diols from Heptalene-1,2-dicarboxylates and Lithiomethyl Phenyl Sulfones. -Optimized reaction conditions allow the transformation of the heptalene (I) with various lithiomethyl aryl sulfones to the desired title diols without formation of any by-product. Halogen substituents in the aryl sulfones are partly or completely replaced by hydrogen. No diols are obtained with the sulfones (VIII). -(LUTZ,


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