ChemInform Abstract: Formation of 3-Sulfonyl-Substituted Benzo[1]heptalene-2,4-diols from Heptalene-1,2-dicarboxylates and Lithiomethyl Phenyl Sulfones.
β Scribed by Marc Lutz; Anthony Linden; Khaled Abou-Hadeed; Hans-Juergen Hansen
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 33 KB
- Volume
- 30
- Category
- Article
- ISSN
- 0931-7597
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β¦ Synopsis
fused phenylcycloalkyl derivatives fused phenylcycloalkyl derivatives (rings with 3, 4, 7 or more members) Q 1040 45 -111 Formation of 3-Sulfonyl-Substituted Benzo[1]heptalene-2,4-diols from Heptalene-1,2-dicarboxylates and Lithiomethyl Phenyl Sulfones. -Optimized reaction conditions allow the transformation of the heptalene (I) with various lithiomethyl aryl sulfones to the desired title diols without formation of any by-product. Halogen substituents in the aryl sulfones are partly or completely replaced by hydrogen. No diols are obtained with the sulfones (VIII). -(LUTZ,
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