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ChemInform Abstract: Formation and Stability of the Gaseous Species LiAlCl4, Li2AlCl5 and LiAl2Cl7 — Mass Spectrometric and Quantum Chemical Studies.

✍ Scribed by H. Saal; E. Milke; C. Bruenig; M. Binnewies; R. Koeppe

Publisher
John Wiley and Sons
Year
2008
Weight
26 KB
Volume
39
Category
Article
ISSN
0931-7597

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Formation and Stability of the Gaseous S
Formation and Stability of the Gaseous Species LiAlCl4, Li2AlCl5 and LiAl2Cl7 – Mass Spectrometric and Quantum Chemical Studies
✍ H. Saal; E. Milke; C. Brünig; M. Binnewies; R. Köppe 📂 Article 📅 2008 🏛 John Wiley and Sons 🌐 English ⚖ 365 KB

## Abstract The formation of the gaseous species LiCl, Li~2~Cl~2~, AlCl~3~ and LiAlCl~4~ was shown by mass spectrometric studies of the reaction of solid LiCl with gaseous AlCl~3~ at 575 °C. Besides AlCl~3~ and Al~2~Cl~6~, the gas complexes LiAlCl~4~, Li~2~AlCl~5~ and LiAl~2~Cl~7~ were formed durin