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ChemInform Abstract: Formal Asymmetric Synthesis of (-)-Aphanorphine via Ring-Closing Metathesis Reaction.

✍ Scribed by Xiaobao Yang; Bin Cheng; Zhong Li; Hongbin Zhai

Publisher: John Wiley and Sons
Year: 2009
Weight: 24 KB
Volume: 40
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.200913206

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Cyclic Sulfonamides via the Ring-Closing Metathesis Reaction. -Ring closing metathesis of various allyl-and vinylsulfonylamides in the presence of Grubb's ruthenium catalyst yields novel cyclic allyl-and vinylsultams. In the case of substrate (IX), the pyrrole (X) is formed instead of the expected