✦ LIBER ✦

ChemInform Abstract: Fluorodesilylations of Fluorophenyltrimethylsilanes with Elemental Fluorine: Discovery of a Novel 1,2-Migration of the Trimethylsilyl Group.

✍ Scribed by A. M. STUART; P. L. COE; D. J. MOODY

Publisher: John Wiley and Sons
Year: 2010
Weight: 33 KB
Volume: 29
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.199833205

No coin nor oath required. For personal study only.

✦ Synopsis

1998 organo-silicon compounds, isocyclic C derivatives organo-silicon compounds, isocyclic C derivatives S 0064 33 -205 Fluorodesilylations of Fluorophenyltrimethylsilanes with Elemental Fluorine: Discovery of a Novel 1,2-Migration of the Trimethylsilyl Group. -The main product in the direct fluorination of silanes is produced by ipso electrophilic substitution of the Tms group, cf. compounds (II), (VI), and (IV). A novel 1,2-migration of the Tms group also occurs leading to the products (III), (IX), and (XII). -(STUART, A.

📜 SIMILAR VOLUMES

ChemInform Abstract: Novel Formation of

ChemInform Abstract: Novel Formation of 1,2,4-Triselenolanes by the Reaction of tert-Butylarylmethylenetriphenylphosphoranes with Elemental Selenium.

✍ Kentaro Okuma; Tomoaki Kubota 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 28 KB 👁 1 views

## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable v

ChemInform Abstract: Unexpected Isomeriz

ChemInform Abstract: Unexpected Isomerization in the Series of Fluorine-Containing 2,3-Dihydro-1H-1,4-diazepines with a 2-Aminoethyl Group at one of the Nitrogen Atoms.

✍ Vyacheslav Sosnovskikh; Ivan I. Vorontsov; Valentin A. Kutsenko; Yurii G. Yatluk 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 29 KB 👁 2 views

ChemInform Abstract: Novel Reactions of

ChemInform Abstract: Novel Reactions of Arylmalonate Carbanions. The Reaction with Phenyl Isocyanate Resulting in Carbamates by 1,3-C→N Migration of the Ethoxycarbonyl Group.

✍ O. A. Linchenko; I. Yu. Krasnova; P. V. Petrovskii; I. A. Garbuzova; V. N. Khrus 📂 Article 📅 2008 🏛 John Wiley and Sons ⚖ 22 KB 👁 1 views

ChemInform Abstract: Cycloaddition of 6-

ChemInform Abstract: Cycloaddition of 6-Hydroxy-2,6-dimethylcyclohexa-2,4-dienone: A Stereoselective Entry into Functionalized Bicyclo[2.2.2]octanes and a Novel 1,2-Migration of Methyl Group.

✍ Vishwakarma Singh; Girish Chandra; Shaikh M. Mobin 📂 Article 📅 2009 🏛 John Wiley and Sons ⚖ 24 KB

## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable v

ChemInform Abstract: 1,2-Alkyl Migration

ChemInform Abstract: 1,2-Alkyl Migration as a Key Element in the Invention of Cascade Reactions Catalyzed by π-Acids

✍ Benedikt Crone; Stefan F. Kirsch 📂 Article 📅 2008 🏛 John Wiley and Sons ⚖ 12 KB 👁 2 views

ChemInform Abstract: Novel 4-(Trimethyls

ChemInform Abstract: Novel 4-(Trimethylsilyl)aminoalkanes and 4-(Trimethylsilyl)aminoalk-2-enes, via a 1,5-Hydride Shift, in the Reaction of α-Unsaturated Silanes with Aminomethylbenzotriazoles.

✍ Carine Churlaud; Jacques Pornet; Daniela C. Oniciu; Alan R. Katritzky 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 38 KB 👁 1 views