ChemInform Abstract: First Synthesis of ortho-Trifluoromethylated Aryl Triflates.
β Scribed by F.-L. QUING; J. FAN; H.-B. SUN; X.-J. YUE
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 35 KB
- Volume
- 29
- Category
- Article
- ISSN
- 0931-7597
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β¦ Synopsis
First Synthesis of ortho-Trifluoromethylated Aryl Triflates.
-A very useful approach is used for the preparation of the title triflates, e.g. (IV), (VI) and (XI). This efficient methodology is applied in the synthesis of the retinoid derivative (XIII). -(QUING, F.
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Palladium-Catalyzed Amination of Aryl Triflates. -The first examples of palladium-catalyzed amination of readily available aryl triflates is presented. Best yields of amines are obtained using electronically neutral or electron-rich aryl triflates. -(WOLFE,