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ChemInform Abstract: First Synthesis of Bi- and Tricyclic α,β-Unsaturated δ-Oxacaprolactams from Cyclic Imines via Ring-Closing Metathesis.

✍ Scribed by Martin Watzke; Knut Schulz; Katharina Johannes; Pasqual Ullrich; Juergen Martens

Publisher: John Wiley and Sons
Year: 2008
Weight: 40 KB
Volume: 39
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.200848161

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Three-Component or Four-Component Coupling Reactions Leading to δ -Lactams. Facile Synthesis of γ-Acyl-δ-lactams from Silyl Enolates, α,β-Unsaturated Thioesters, and Imines or Amines and Aldehydes via Tandem Michael-Imino Aldol Reactions. -The Michael reaction of silyl enol ethers and unsaturated t