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ChemInform Abstract: First Example of a Claisen Rearrangement Stereocontrolled by a Sulfinyl Group: Synthesis of Novel α-Sulfinyl Dithioesters.

✍ Scribed by C. ALAYRAC; C. FROMONT; P. METZNER; NGUYEN TRONG ANH NGUYEN TRONG ANH


Publisher
John Wiley and Sons
Year
2010
Weight
31 KB
Volume
28
Category
Article
ISSN
0931-7597

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✍ Tetsuo Iwama; Tadashi Kataoka; Osamu Muraoka; Genzoh Tanabe 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 34 KB

A New Synthesis of α-Amino Acid Thioesters by Pummerer Reaction of 3-Substituted-4-sulfinyl-β-sultams. -trans-Sultams (I), (V), and (VII), obtained in all cases as two separable epimers at the sulfoxide group, are each converted to the title thioesters via sulfenylation and Pummerer rearrangement w