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ChemInform Abstract: First Asymmetric Synthesis of (Un)saturated 1-Alkylbenzo[c]azepin-3-ones: Extension to the Corresponding Benzazepines.

✍ Scribed by David Dumoulin; Stephane Lebrun; Eric Deniau; Axel Couture; Pierre Grandclaudon

Publisher: John Wiley and Sons
Year: 2009
Weight: 44 KB
Volume: 40
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.200950187

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First Asymmetric Synthesis of (Un)satura

First Asymmetric Synthesis of (Un)saturated 1-Alkylbenzo[c]azepin-3-ones: Extension to the Corresponding Benzazepines

✍ David Dumoulin; Stéphane Lebrun; Eric Deniau; Axel Couture; Pierre Grandclaudon 📂 Article 📅 2009 🏛 John Wiley and Sons 🌐 English ⚖ 294 KB

## Abstract A flexible route for the stereoselective synthesis of a variety of structurally diverse (__1R__)‐1‐alkyldihydro and tetrahydrobenzazepin(ones) has been developed. The key step is a highly diastereoselective 1,2‐addition process applied to a stereopure aromatic hydrazone combined with a

ChemInform Abstract: Alternative and Com

ChemInform Abstract: Alternative and Complementary Approach to the Asymmetric Synthesis of C3 Substituted NH Free or N-Substituted Isoindolin-1-ones.

✍ Marc Lamblin; Axel Couture; Eric Deniau; Pierre Grandclaudon 📂 Article 📅 2008 🏛 John Wiley and Sons ⚖ 87 KB