✦ LIBER ✦
ChemInform Abstract: Fascinating Reactivity in Gold Catalysis: Synthesis of Oxetenes Through Rare 4-exo-dig Allene Cyclization and Infrequent β-Hydride Elimination.
✍ Scribed by Benito Alcaide; Pedro Almendros; Teresa Martinez del Campo; Israel Fernandez
- Publisher
- John Wiley and Sons
- Year
- 2011
- Weight
- 33 KB
- Volume
- 42
- Category
- Article
- ISSN
- 0931-7597
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✦ Synopsis
Abstract
The substitution pattern of the allenol substrate determines the reaction outcome of the gold‐catalyzed cyclization to yield either dihydrofurans (II)/(VI) or oxetenes (IV)/(VII).