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ChemInform Abstract: Facile Synthesis and Conformation of 3′-O,4′-C-Methyleneribonucleosides.

✍ Scribed by Satoshi Obika; Ken-ichiro Morio; Yoshiyuki Hari; Takeshi Imanishi

Publisher
John Wiley and Sons
Year
2010
Weight
34 KB
Volume
31
Category
Article
ISSN
0931-7597

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Facile Synthesis of Furan-3,4-diacetates. -Rhodium-catalyzed bis-cyclopropanation of furan derivatives (I) with excess amounts of diazocarboxylates (II) followed by selective cyclopropane ring opening in ethanolic HCl provides access to furan-3,4-diacetates (IV) or -propionates. -(WENKERT,