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ChemInform Abstract: Facile One-Pot Preparation of Functionalized Bicyclo(4.2.1)nonan-9-one Precursors of Carbocyclic Eight-Membered Rings.

✍ Scribed by T. LAVOISIER; J. RODRIGUEZ


Book ID
112030526
Publisher
John Wiley and Sons
Year
2010
Weight
31 KB
Volume
27
Category
Article
ISSN
0931-7597

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ChemInform Abstract: Stereochemistry. Pa
✍ I. N. N. NAMBOOTHIRI; A. HASSNER; H. E. GOTTLIEB πŸ“‚ Article πŸ“… 2010 πŸ› John Wiley and Sons βš– 32 KB πŸ‘ 1 views

Strategy for the Construction of Functionalized Five-and Six-Membered Carbocycles. -Conjugate addition of the Grignard reagents (II) and (IV) to the nitro olefins (I) leads to the intermediate formation of nitronates, which are trapped as silyl nitronates and subsequently cyclized by intramolecular