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ChemInform Abstract: Facile Conversion of Epoxides to Thiiranes with Ammonium Thiocyanate Catalyzed with Etidronic Acid.

✍ Scribed by Liqiang Wu; Yongxue Wang; Fulin Yan; Chunguang Yang


Publisher
John Wiley and Sons
Year
2010
Weight
26 KB
Volume
41
Category
Article
ISSN
0931-7597

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✦ Synopsis


Abstract

Thiiranes are formed from epoxides when treated with NH~4~SCN in boiling THF using etidronic acid as catalyst.


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Conversion of Epoxides to Thiiranes Catalyzed with TiO(TFA) 2 and TiCl 3 (OTf ) in the Presence of Ammonium Thiocyanate or Thiourea. -TiO(O-CO-CF 3 ) 2 and TiCl 3 (O-Tf) prove to be efficient catalysts for the conversion of epoxides to thiiranes with both NH 4 SCN or thiourea under aprotic conditio

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