ChemInform Abstract: Facile Conversion of Epoxides to Thiiranes with Ammonium Thiocyanate Catalyzed with Etidronic Acid.
β Scribed by Liqiang Wu; Yongxue Wang; Fulin Yan; Chunguang Yang
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 26 KB
- Volume
- 41
- Category
- Article
- ISSN
- 0931-7597
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β¦ Synopsis
Abstract
Thiiranes are formed from epoxides when treated with NH~4~SCN in boiling THF using etidronic acid as catalyst.
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Conversion of Epoxides to Thiiranes Catalyzed with TiO(TFA) 2 and TiCl 3 (OTf ) in the Presence of Ammonium Thiocyanate or Thiourea. -TiO(O-CO-CF 3 ) 2 and TiCl 3 (O-Tf) prove to be efficient catalysts for the conversion of epoxides to thiiranes with both NH 4 SCN or thiourea under aprotic conditio
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