✦ LIBER ✦
ChemInform Abstract: Facile Construction of the Tricyclo[5.2.1.01,5]decane Ring System by Intramolecular Double Michael Reaction: Highly Stereocontrolled Total Synthesis of (.+-.)-8,14-Cedranediol and (.+-.)-8,14-Cedranoxide.
✍ Scribed by Masataka Ihara; Kei Makita; Kiyosei Takasu
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 36 KB
- Volume
- 30
- Category
- Article
- ISSN
- 0931-7597
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✦ Synopsis
Facile Construction of the Tricyclo[5.2.1.0 1,5 ]decane Ring System by Intramolecular Double Michael Reaction: Highly Stereocontrolled Total Synthesis of (±)-8,14-Cedranediol and (±)-8,14-Cedranoxide. -Intramolecular double Michael reaction of cyclopentenone (I) is the key step in the synthesis of racemic cedranediol (III) and cedranoxide (IV) from 4-(1-cyclopenten-1-yl)morpholine. -(IHARA, MASATAKA; MAKITA, KEI;