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ChemInform Abstract: Facile Chlorination of Benzyl Alcohols Using 1,8-Diazabicyclo[5.4.0]undec-7-ene (DBU) and Sulfonyl Chlorides.

โœ Scribed by Hyung Woo Kim; Yun-Sang Lee; Dinesh Shetty; Hak Jeong Lee; Dong-Soo Lee; June-Key Chung; Myung Chul Lee; Kyoo-Hyun Chung; Jae Min Jeong


Publisher
John Wiley and Sons
Year
2011
Weight
27 KB
Volume
42
Category
Article
ISSN
0931-7597

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Diazabicyclo( 5.4 .0)undec-7-ene. -Treatment of halogen compounds (I) with DBU is investigated in order to obtain fluorinated dienes for cycloaddition reactions. However, the expected products (cf. (II)) are only obtained in the case of aryl substituents. Alkyl, cycloalkyl and alkoxy substituents