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ChemInform Abstract: Facile and Selective Formation of a Linear-Triquinane Skeleton by a Rationally Designed Round Trip Radical Reaction.

โœ Scribed by Kiyosei Takasu; Soumen Maiti; Akira Katsumata; Masataka Ihara

Book ID
101912142
Publisher
John Wiley and Sons
Year
2010
Weight
28 KB
Volume
32
Category
Article
ISSN
0931-7597

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Facile and selective formation of a line
Facile and selective formation of a linear-triquinane skeleton by a rationally designed round trip radical reaction
โœ Kiyosei Takasu; Soumen Maiti; Akira Katsumata; Masataka Ihara ๐Ÿ“‚ Article ๐Ÿ“… 2001 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 74 KB

The radical reaction of 1-iodo-1,5,10-trienoate afforded a linear fused five-membered carbocycle. Another key feature of this reaction is the remarkable acceleration of the reaction rate and enhancement of selectivity caused by the introduction of a conjugated ester moiety at the terminal olefin. Th