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ChemInform Abstract: Facile Acylation of Sterically Hindered Alcohols Through Ketene Intermediates.

โœ Scribed by Moshe Nahmany; Artem Melman

Publisher
John Wiley and Sons
Year
2010
Weight
30 KB
Volume
33
Category
Article
ISSN
0931-7597

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โœ S. I. Shergina; A. S. Zanina; I. E. Sokolov; M. S. Shvartsberg ๐Ÿ“‚ Article ๐Ÿ“… 2010 ๐Ÿ› John Wiley and Sons โš– 29 KB ๐Ÿ‘ 1 views

Acylation of Sterically Hindered 2-Propargyl-1,3-diketones. -The acylation of sterically hindered propargyl-substituted 1,3-diketones (I) by acyl chlorides occurs selectively at the terminal acetylenic group in the presence of CuCl. Some peculiarities of this reaction are reported. -(SHERGINA, S. I.