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ChemInform Abstract: Extension of π-Conjugation Length via the Vacant p-Orbital of the Boron Atom. Synthesis of Novel Electron Deficient π-Conjugated Systems by Hydroboration Polymerization and Their Blue Light Emission.

✍ Scribed by N. MATSUMI; K. NAKA; Y. CHUJO


Publisher
John Wiley and Sons
Year
2010
Weight
32 KB
Volume
29
Category
Article
ISSN
0931-7597

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✦ Synopsis


Extension of π-Conjugation Length via the Vacant p-Orbital of the Boron Atom. Synthesis of Novel Electron Deficient π-Conjugated Systems by Hydroboration Polymerization and Their Blue Light Emission.

-A series of conjugated organoboron polymers is synthesized from mesitylborane (I) and aromatic diynes (II). The novel π-conjugated polymers are highly soluble in common organic solvents and show a blue fluorescence emission. -(MATSUMI, N.;