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ChemInform Abstract: EQCM Study of Iron Deposition from Fe(II)/Fe(III)(EDTA) Solutions.

✍ Scribed by E. JUZELIUNAS; K. JUETTNER

Publisher: John Wiley and Sons
Year: 2010
Weight: 30 KB
Volume: 29
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.199835018

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✦ Synopsis

EQCM Study of Iron Deposition from Fe(II)/Fe(III)(EDTA) Solutions.

-The complex polarization behavior of Fe(II)(EDTA) and Fe(III)(EDTA) is studied on a Pt rotating disc electrode. A mass increase of the electrode, indicating iron deposition, is found at potentials below -1.0 V vs. SCE, i.e. in the region where the cathodic H 2 O decomposition takes place. A limiting deposition rate is indicated by a linear mass increase during the potential sweep. The results imply that Fe deposition takes place by a diffusion controlled process.

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