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ChemInform Abstract: Episulfidation of Strained Cycloalkenes in the Thermolysis of 5-Aryloxy-1,2,3,4-thiatriazoles.

✍ Scribed by Waldemar Adam; R. M. Bargon

Publisher
John Wiley and Sons
Year
2010
Weight
27 KB
Volume
33
Category
Article
ISSN
0931-7597

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Episulfidation of Strained Cycloalkenes
Episulfidation of Strained Cycloalkenes in the Thermolysis of 5-Aryloxy-1,2,3,4-thiatriazoles
✍ Waldemar Adam; RainerΒ M. Bargon πŸ“‚ Article πŸ“… 2001 πŸ› John Wiley and Sons 🌐 English βš– 240 KB πŸ‘ 1 views

The thermolysis of 5-aryloxythiatriazoles 1 in the presence of norbornene (2a) and trans-cyclooctene (trans-2b) affords the corresponding thiiranes 3a and trans-3b in moderate yields. First-order kinetics are observed, suggesting that a sulfur in- [a]