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ChemInform Abstract: Enzymatic Preparation of (S)-3-Hydroxytetradecanoic Acid and Synthesis of Unnatural Analogues of Lipid A Containing the (S)-Acid.

✍ Scribed by W.-C. LIU; M. OIKAWA; K. FUKASE; Y. SUDA; H. WINARNO; S. MORI; M. HASHIMOTO; S. KUSUMOTO

Publisher
John Wiley and Sons
Year
2010
Weight
29 KB
Volume
28
Category
Article
ISSN
0931-7597

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Enantiospecific enzymatic preparation of
Enantiospecific enzymatic preparation of (2S,3S)-3-alkylaspartic acids of current interest in the synthesis of stereoregular poly[Ξ²-(2S,3S)-3-alkylmalic acids] as new optically active functional polyesters
✍ Claire Monne; Daniel Robic; GeneviΓ¨ve Campion; Richard Bourbouze; Alain Rimbault πŸ“‚ Article πŸ“… 1996 πŸ› John Wiley and Sons 🌐 English βš– 479 KB πŸ‘ 2 views

2S,3S)-3-methyl-and 3-isopropylaspartic acids were synthesized by bioconversion of the corresponding alkylfumarates (mesaconate and 3-isopropylfumarate) using pmethylaspartase from cell-free extracts of Clostridium tetanomorphum. Optically pure (2S,3S)-3-alkylaspartic acids were transformed in sever