ChemInform Abstract: Environmentally Benign Regio- and Stereoselective Synthesis of Functionalized Tertiary Amines.

✍ Scribed by Rendong Wang; Jian Li; Chunju Li; Jun Liu; Dafeng Li; Xueshun Jia; Hongbin Zhai

• Publisher: John Wiley and Sons
• Year: 2010
• Weight: 21 KB
• Volume: 41
• Category: Article
• ISSN: 0931-7597
• DOI: 10.1002/chin.201048056

✦ Synopsis

Abstract

Baylis—Hillman adducts (I) react regio‐ and stereoselectively with various primary aliphatic amines under neat conditions to potentially valuable building blocks containing reactive C—C double bonds and an ester and cyano group, respectively.