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ChemInform Abstract: Enthalpy, Heat Capacity, Second-Order Transitions and Enthalpy of Fusion of Li4SiO4 by High-Temperature Calorimetry.

✍ Scribed by H. KLEYKAMP

Publisher
John Wiley and Sons
Year
2010
Weight
29 KB
Volume
28
Category
Article
ISSN
0931-7597

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✦ Synopsis

The enthalpy is measured by isothermal drop calorimetry between 363 and 1300 K and anisothermal calorimetry is used for the identifications of two second-order transitions and the measurement of enthalpy of fusion. A smoothed curve of the experimental points of the enthalpy fitted to a polynomial H β€’ (T)-H β€’ (298) = a + bT + cT2 + dT-1 by the least squares method gives -17156 + 73.694 T + 0.

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