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ChemInform Abstract: Enhanced Diastereoselectivity in the Asymmetric Ugi Reaction Using a New “Convertible” Isonitrile.

✍ Scribed by Russell J. Linderman; Sophie Binet; Samantha R. Petrich

Publisher
John Wiley and Sons
Year
2010
Weight
29 KB
Volume
30
Category
Article
ISSN
0931-7597

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Towards Molecular Diversity: Dealkylation of tert-Butyl Amine in Ugi-Type Multicomponent Reaction Product Establishes tert-Butyl Isocyanide as a Useful Convertible Isonitrile. -The dealkylation of an alkylamine, in situ generated during Ugi reaction with tert-butyl isonitrile (III), is smoothly achi