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ChemInform Abstract: Enethiol Assisted (3,4) and (3,5) Sigmatropic Rearrangements During Thionation of 2,3-Diaroylbicyclo(2.2.1)hepta-5-enes with Boron Sulfide.

✍ Scribed by D. S. H. L. KIM; F. FREEMAN


Book ID
101841639
Publisher
John Wiley and Sons
Year
2010
Weight
32 KB
Volume
28
Category
Article
ISSN
0931-7597

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Enethiol assisted [3,4] and [3,5] sigmat
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Thionation reaction of 2,3-diaroylbicyclo[2.2.1]hepta-5-enes using in situ generated B2S 3 (bis-trialkyltin sulfide or bis-trimethylsilyl sulfide reacted with BCI 3 in toluene) gave [3,4] and [3,5] sigmatropic rearrangement products.

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