ChemInform Abstract: Enantiospecific Synthesis of the 14-Membered Diene Unit of Methyl Sarcophytoate

✍ Scribed by M. YASUDA; M. IDE; Y. MATSUMOTO; M. NAKATA

• Publisher: John Wiley and Sons
• Year: 2010
• Weight: 25 KB
• Volume: 28
• Category: Article
• ISSN: 0931-7597
• DOI: 10.1002/chin.199750191

✦ Synopsis

Enantiospecific Synthesis of the 14-Membered Diene Unit of Methyl Sarcophytoate -((I) in a 28-step synthesis starting from geraniol using Sharpless asymmetric epoxidation, aldol reaction, oxy-Michael addition and a modified Ito-Kodama cyclization as key steps). -(YASUDA, M.; IDE,