ChemInform Abstract: Enantioselective Trifluoromethylation of Ketones with (Trifluoromethyl)trimethylsilane Catalyzed by Chiral Quaternary Ammonium Phenoxides.
β Scribed by Hitoshi Nagao; Yoshikazu Kawano; Teruaki Mukaiyama
- Publisher
- John Wiley and Sons
- Year
- 2008
- Weight
- 43 KB
- Volume
- 39
- Category
- Article
- ISSN
- 0931-7597
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β¦ Synopsis
Abstract
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π SIMILAR VOLUMES
Cesium Fluoride Catalyzed Trifluoromethylation of Esters, Aldehydes, and Ketones with (Trifluoromethyl)trimethylsilane. -The title reaction is successfully applied to carboxylic, sulfonic, sulfinic, and selenic esters, and also to aldehydes and ketones, among them substrates that have been reported