ChemInform Abstract: Enantioselective Synthesis of γ-Lactones from Thioglycolic Acid: Syntheses of (-)-Muricatacin and 5-epi-(-)-Muricatacin.
✍ Scribed by S.-W. CHANG; C.-Y. HUNG; H.-H. LIU; B.-J. UANG
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 37 KB
- Volume
- 29
- Category
- Article
- ISSN
- 0931-7597
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New and Efficient Enantiospecific Synthesis of (-)-Methyl 5-epi-Shikimate and Methyl 5-epi-Quinate from (-)-Quinic Acid. -Starting from (-)-quinic acid (I) as readily available and inexpensive educt, (-)-methyl 5-epi-shikimate (VI) and methyl 5-epi-quinate (XI) are prepared. The key sequence invol