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ChemInform Abstract: Enantioselective Synthesis of threo-α,β-Dihydroxyphosphonates by Asymmetric Dihydroxylation of 1(E)-Alkenylphosphonates with AD-mix Reagents.

✍ Scribed by T. YOKOMATSU; T. YAMAGISHI; K. SUEMUNE; Y. YOSHIDA; S. SHIBUYA


Publisher
John Wiley and Sons
Year
2010
Weight
38 KB
Volume
29
Category
Article
ISSN
0931-7597

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ChemInform Abstract: Asymmetric Dihydrox
✍ T. YOKOMATSU; T. YAMAGISHI; T. SADA; K. SUEMUNE; S. SHIBUYA 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 38 KB 👁 1 views

Asymmetric Dihydroxylation of 1-Acyloxy-2(E)-alkenylphosphonates with AD-mix Reagents. Effects of 1-Acyloxy Functional Groups on the Asymmetric Dihydroxylation. -The reaction of a racemic mixture of the title phosphonates with an AD-mix-β reagent preferentially dihydroxylates the (R)-enantiomer to l