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ChemInform Abstract: Enantioselective Synthesis of Ethyl 4,5,7,8,9-Penta-O-acetyl-2,6-anhydro-3-deoxy-D-erythro-L-gluca-nononate: A 2-Monodeoxygenated Derivative of “2-Keto-3-deoxy-D-glycero-D-galacto-nononic Acid”.

✍ Scribed by Xin Shen; Yu-Lin Wu; Yikang Wu

Publisher
John Wiley and Sons
Year
2010
Weight
39 KB
Volume
31
Category
Article
ISSN
0931-7597

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✦ Synopsis

Abstract

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📜 SIMILAR VOLUMES

Enantioselective Synthesis of Ethyl 4,5,
Enantioselective Synthesis of Ethyl 4,5,7,8,9-Penta-O-acetyl-2,6-anhydro- 3-deoxy-D-erythro-L-gluca-nononate: a 2-Monodeoxygenated Derivative of `2-Keto-3-deoxy-D-glycero-D-galacto-nononic Acid'
✍ Xin Shen; Yu-Lin Wu; Yikang Wu 📂 Article 📅 2000 🏛 John Wiley and Sons 🌐 German ⚖ 203 KB 👁 1 views

A study aimed at developing an enantioselective synthesis of the title compound 23, a 2-monodeoxy analogue of the naturally occurring ()-2-keto-3-deoxy-d-glycero-d-galacto-2-nononic acid (KDN), is reported. From d-mannose as starting material, the chiral 1,3-diene 10, activated by a silyloxy substit