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ChemInform Abstract: Enantioselective Reformatsky Reaction of Methyl Bromodifluoroacetate.

✍ Scribed by M. BRAUN; A. VONDERHAGEN; D. WALDMUELLER

Book ID
112023687
Publisher
John Wiley and Sons
Year
2010
Weight
27 KB
Volume
26
Category
Article
ISSN
0931-7597

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Enantioselective reformatsky reaction of
Enantioselective reformatsky reaction of methyl bromodifluoroacetate
✍ Braun, Manfred ;Vonderhagen, Anja ;WaldmΓΌller, Delia πŸ“‚ Article πŸ“… 1995 πŸ› John Wiley and Sons 🌐 English βš– 386 KB

## Abstract The Reformatsky reagent 2 generated from methyl bromodifluoroacetate is added to benzaldehyde in the presence of carbinols 3a, b, amino alcohols 3c‐g, or amino alkoxide 3h. __N__‐Methylephedrine 3c provides the highest enantioselectivity in the formation of the adduct __S__‐4a (84% ee;