ChemInform Abstract: Enantioselective ortho-Lithiation of Benzaldehyde Chromiumtricarbonyl Complex.
β Scribed by A. ALEXAKIS; T. KANGER; P. MANGENEY; F. ROSE-MUNCH; A. PERROTEY; E. ROSE
- Book ID
- 112027198
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 28 KB
- Volume
- 27
- Category
- Article
- ISSN
- 0931-7597
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π SIMILAR VOLUMES
The ayymmetric ortho lithiation of aminals of benzaldehyde chromiumtriearbonyl complex is described. The best regioisomeric composition is attained with aminal 2d. Quenching with an electrophile and hydrolysis of the aminal back to the aldehyde afford a single enantiomer of the o-substituted benzald
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