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ChemInform Abstract: Enantioselective Organocatalytic Friedel—Crafts Alkylation Reaction of Indoles with 5-Hydroxyfuran-2(5H)-one: Access to Chiral γ-Lactones and γ-Lactams via a Ugi 4-Center 3-Component Reaction.

✍ Scribed by Emmanuel Riguet


Publisher
John Wiley and Sons
Year
2012
Weight
58 KB
Volume
43
Category
Article
ISSN
0931-7597

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✦ Synopsis


Abstract

The prolinol‐catalyzed treatment of indoles with the furanone (II) followed by reduction and lactonization provides an efficient approach to chiral lactones of type (III) and (IX).