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ChemInform Abstract: Enantioselective Organo-SOMO Catalysis: The α-Vinylation of Aldehydes.

✍ Scribed by Hahn Kim; David W. C. MacMillan

Publisher
John Wiley and Sons
Year
2008
Weight
58 KB
Volume
39
Category
Article
ISSN
0931-7597

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## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable v

Enantioselective Linchpin Catalysis by S
Enantioselective Linchpin Catalysis by SOMO Catalysis: An Approach to the Asymmetric α-Chlorination of Aldehydes and Terminal Epoxide Formation
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## Abstract Dreh‐ und Angelpunkt: Erstmals wurde eine SOMO‐Aktivierung genutzt, um Aldehyde in α‐Stellung zu chlorieren. Diese Umwandlung lässt sich als Teil eines „Linchpin“‐Katalyseprozesses einsetzen, der die enantioselektive Synthese terminaler Epoxide ermöglicht (siehe Schema).magnified image