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ChemInform Abstract: Enantioselective Intramolecular Crossed Rauhut—Currier Reactions Through Cooperative Nucleophilic Activation and Hydrogen-Bonding Catalysis: Scope and Mechanistic Insight.

✍ Scribed by Xu-Fan Wang; Liang Peng; Jing An; Chao Li; Qing-Qing Yang; Liang-Qiu Lu; Feng-Long Gu; Wen-Jing Xiao

Publisher
John Wiley and Sons
Year
2011
Weight
37 KB
Volume
42
Category
Article
ISSN
0931-7597

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Enantioselective Intramolecular Crossed
Enantioselective Intramolecular Crossed Rauhut–Currier Reactions through Cooperative Nucleophilic Activation and Hydrogen-Bonding Catalysis: Scope and Mechanistic Insight
✍ Xu-Fan Wang; Liang Peng; Jing An; Chao Li; Qing-Qing Yang; Liang-Qiu Lu; Prof. D 📂 Article 📅 2011 🏛 John Wiley and Sons 🌐 English ⚖ 428 KB

## Abstract A highly efficient and enantioselective intramolecular crossed Rauhut–Currier (RC) reaction of nitroolefins with tethered enonates has been developed through cooperative nucleophilic activation and a hydrogen‐bonding catalytic strategy (≤98 % __ee__ and 98 % yield). The reaction feature