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ChemInform Abstract: Enantioselective Hydrogenation of α,β-Unsaturated Ketones over Palladium on Charcoal in the Presence of (-)-Ephedrine.

✍ Scribed by C. THOREY; F. HENIN; J. MUZART

Book ID
112036609
Publisher
John Wiley and Sons
Year
2010
Weight
31 KB
Volume
27
Category
Article
ISSN
0931-7597

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Enantioselective hydrogenation of exocyc
Enantioselective hydrogenation of exocyclic α,β-unsaturated ketones: Part II. Hydrogenation in the presence of (S)-proline
✍ Gabriella Fogassy; Antal Tungler; Albert Lévai; Gábor Tóth 📂 Article 📅 2002 🏛 Elsevier Science 🌐 English ⚖ 74 KB

In the asymmetric synthesis of chiral compounds, the reduction of prochiral unsaturated reactants has a great importance. (S)-proline as a chiral auxiliary is used in the hydrogenations of exocyclic ␣,␤-unsaturated ketones with palladium on carbon catalysts, producing the corresponding saturated ke