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ChemInform Abstract: Enantioselective Friedel—Crafts Alkylations Catalyzed by Well-Defined Iridium and Rhodium Half-Sandwich Complexes.

✍ Scribed by Daniel Carmona; Maria Pilar Lamata; Antonio Sanchez; Fernando Viguri; Luis A. Oro

Publisher
John Wiley and Sons
Year
2011
Weight
40 KB
Volume
42
Category
Article
ISSN
0931-7597

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✦ Synopsis

Abstract

Cationic Rh or Ir—bisphosphine complexes catalyze the Friedel—Crafts alkylation of various electron‐rich arenes as well as indole derivatives with trans‐crotonaldehyde (II), methacrolein (IV) or β‐nitrostyrenes (IX).

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