ChemInform Abstract: Enantioselective Cyclopropanation of Allylic Alcohols. The Effect of Zinc Iodide.
β Scribed by S. E. DENMARK; S. P. O'CONNOR
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 28 KB
- Volume
- 28
- Category
- Article
- ISSN
- 0931-7597
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π SIMILAR VOLUMES
Directing Effect of a Neighboring Aromatic Group in the Cyclopropanation of Allylic Alcohols. -Various racemic allylic alcohols are stereoselectively transformed to cyclopropanes with I-CH 2 -Cl in the presence of either zinc or samarium reagent. Alcohols bearing an aryl group at the stereocenter a
Enantioselective Cyclopropanation of Allylic Alcohols with Dioxaborolane Ligands: Scope and Synthetic Applications. -Chiral dicarboxamidodioxaborolane is found to be a very efficient chiral controller for the conversion of allylic alcohols (I) to enantiomeric cyclopropylmethanols (III) using bis(io
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