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ChemInform Abstract: Enantioselective Construction of Quaternary α-Carbon Centers on α-Amino Phosphonates via Catalytic Asymmetric Allylation.

✍ Scribed by Ryoichi Kuwano; Ryo Nishio; Yoshihiko Ito


Publisher
John Wiley and Sons
Year
2010
Weight
32 KB
Volume
30
Category
Article
ISSN
0931-7597

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## Abstract The addition of (hetero‐)aryl vinyl ketones to the cyclic cyanoketones provides 1,5‐dicarbonyl compounds with good to excellent yields and enantioselectivities with exception of alkyl vinyl ketone (IIa).