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ChemInform Abstract: Enantioselective Conjugate Radical Addition Reactions Mediated by Chiral Lewis Acid Complexes of (R,R)-4,6-Dibenzofurandiyl-2,2′-bis(4-phenyloxazoline) (DBFOX/Ph).

✍ Scribed by Ulrich Iserloh; Dennis P. Curran; Shuji Kanemasa

Publisher
John Wiley and Sons
Year
2010
Weight
33 KB
Volume
30
Category
Article
ISSN
0931-7597

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✦ Synopsis

Enantioselective Conjugate Radical Addition Reactions Mediated by Chiral Lewis Acid Complexes of (R,R)-4,6-Dibenzofurandiyl-2,2'-bis(4-phenyloxazoline) (DBFOX/Ph).

-25 Lewis acids are investigated in the radical addition reaction of isopropyl iodide to unsaturated amide (I) in the presence of chiral ligand (R,R)-Ph-DBFOX. Mg(ClO 4 ) 2 is the only effective LA in terms of enantioselectivity and yield.

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## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable v

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