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ChemInform Abstract: Enantioselective Catalysis. Part 111. New Chiral Expanded Phosphanes Derived from Substituted Deltacyclenes.

✍ Scribed by H. BRUNNER; A. REIMER

Publisher: John Wiley and Sons
Year: 2010
Weight: 28 KB
Volume: 28
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.199752183

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✦ Synopsis

1997 organo-phosphorus compounds, isocyclic C derivatives organo-phosphorus compounds, isocyclic C derivatives S 0084 52 -183 Enantioselective Catalysis. Part 111. New Chiral Expanded Phosphanes Derived from Substituted Deltacyclenes.

-The new ligands (cf. (I)-(III)) are tested in Rh-catalyzed asymmetric hydrogenations. Best results in preliminary studies are obtained with ( II) under the conditions shown.

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